What are the characteristics of calcium fluoride
The natural mineral of calcium fluoride is called fluorite (fluorite). High purity synthesized calcium fluoride crystals are key materials in the optical and semiconductor industries, with the chemical formula CaF ? and an equiaxed cubic crystal structure.
1、 Physical characteristics
1. Appearance: Pure product is colorless transparent crystal or white powder; Natural fluorite presents various colors such as green, purple, blue, and yellow due to impurities, with a glassy luster and brittle nature.
2. Mechanical parameters: Mohs hardness of 4, with a soft texture that is prone to cracking; Density 3.18 g/cm 3; The melting point is about 1423 ℃ and the boiling point is about 2500 ℃.
3. Highlight optical characteristics (core advantage): The transmission band is extremely wide, and both deep ultraviolet, visible light, and infrared can be transmitted; Low refractive index (about 1.434) and low dispersion, making it one of the few ultraviolet optical materials; Fluorescence can be generated under UV, cathode ray, and heating conditions (source of fluorite name).
4. Thermal characteristics: high coefficient of thermal expansion, poor thermal conductivity, weak resistance to thermal shock, rapid alternation of hot and cold, and easy cracking.
5. Solubility characteristics: extremely difficult to dissolve in water, almost insoluble in organic solvents such as acetone; It can only be dissolved in hot concentrated sulfuric acid, concentrated hydrochloric acid, aluminum salt/iron salt solutions (chelation dissolution).
2、 Chemical characteristics
1. Good stability at room temperature: resistant to alkali, most dilute acids, atmospheric corrosion, and strong chemical inertness under normal conditions.
2. Reaction with concentrated sulfuric acid: The reaction generates HF (hydrogen fluoride, a highly corrosive and toxic gas), which is the basic reaction for producing hydrofluoric acid in fluorine chemical industry and also the main safety risk point.
3. High temperature hydrolysis: Under high temperature environments above 800 ℃, it will gradually hydrolyze, generating CaO and releasing hydrogen fluoride; At high temperature, it can form eutectic with a variety of metal oxides, and has the ability to aid melting.
4. Low toxicity: It has low toxicity itself, but the hydrogen fluoride produced by decomposition is highly corrosive and toxic.
3、 Summary of Characteristics Corresponding to Industrial Applications
Low dispersion, wide spectral transmittance: used for UV lenses, infrared windows, lithography machine optical lenses, spectrometer lenses;
Fusing aids and melting point lowering agents: steel and non-ferrous smelting fluxes, glass, ceramics, cement mineralizers;
Stable fluorine source: Basic raw materials for fluorine chemical industry, preparing hydrofluoric acid, fluororesin, and fluorine electronic chemicals;
Corrosion resistant fillers: Some special coatings, lubricants, ceramic fillers.